Imports System.Configuration
Dim config = ConfigurationManager.OpenExeConfiguration(ConfigurationUserLevel.None)
config.AppSettings.Settings("KeyName").Value = "NewValue"
config.Save(ConfigurationSaveMode.Modified)
ConfigurationManager.RefreshSection("appSettings")
OpenExeConfiguration 獲取可寫配置對象(針對當前 exe)。AppSettings.Settings("Key").Value。Save(Modified) 僅寫入已修改節點。RefreshSection 讓後續 ConfigurationManager.AppSettings["Key"] 讀到新值。VB.NET 修改 app.config 完整示例(C# 寫法同理,括號換圓括號)。